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101.
Abstract. Inorganic chemical compositions are determined for late Early Triassic siliceous claystone ('Toishi-type' shale) and associated chert from Oritate area, Sambosan Belt, Kyushu, southwest Japan. The siliceous claystone is similar in chemical composition to Post-Archean Australian Shale (PAAS), but is depleted in Ca, Sr, Mn, and Fe and slightly enriched in Cu, Zn, P, and rare earth elements (REEs). The siliceous claystone and associated chert have flat REE patterns with positive Eu anomalies and no distinct Ce anomaly. The siliceous claystone and associated chert have largely constant Ti/Al, Th/Al, and Nb/Al ratios compared to the variable ratios found in siliceous shale and sandstone deposited close to land in a trench setting. This suggests that the claystone and chert were deposited in a deep-sea pelagic environment and were derived mainly from the suspended fraction, including eolian dust and material transported from distant lands, rather than from turbidity currents that occurred close to land. The low Ca contents of the analyzed rocks indicate deposition below the calcium-carbonate compensation depth. The depletion of Mn and Fe, and no distinct Ce anomaly in the Oritate siliceous claystone are also evident, being similar to those in samples from the Sasayama and Kinkazan sections in the Mino-Tanba Belt, where oceanic anoxia developed during the Late Permian to earliest Triassic. This might suggest that oceanic anoxia prevailed through to the late Early Triassic. 相似文献
102.
Abstract. The occurrence, lithology, and stratigraphic setting of buried manganese deposits and associated host sediments in cores obtained on Legs 123–210 of the Ocean Drilling Program (ODP) are examined in order to establish the formative environment and conditions of preservation. Fossil manganese nodule and crusts are found to have formed or deposited throughout the period from 100 Ma to the present, with an additional example of formation near 137 Ma, suggesting that the deep-sea environment has been oxic and suitable for the formation of manganese nodules and crusts since the Cretaceous. Many manganese nodules and crusts occur on horizons corresponding to hiatuses in sedimentation or periods of slow sedimentation, consistent with the environment in which modern nodules form (sedimentation rate less than 10 m/m.y.). Sediments overlying the fossil nodules and crusts are oozes or biogenic sediments with sedimentation rates of 1–18 m/m.y. Low total organic carbon (<0.1 wt%) in the overlying sediments and high sulfate content (>25 mM) in interstitial water around the manganese horizon suggest that no strong reduction occurred within the overlying sediments. Coverage by biogenic sediments containing only small amounts of organic matter is therefore considered important for the preservation of manganese nodules and crusts. Manganese carbonate occurs sporadically as nodules, concretions or thin layers in various host sediments, including clay, calcareous ooze and siliceous ooze with sedimentation rates of 6–125 m/m.y. Hiatuses are rare around the host sediments of manganese carbonate. Higher total organic carbon (0.2–1.8 wt%) in the host sediments and lower sulfate content (0–25 mM) in interstitial water around the manganese carbonate horizon suggest that reduction in association with decomposition of organic matter would have proceeded in the host sediments. 相似文献
103.
104.
Abstract. Germanium‐bearing colusite occurs with sphalerite, galena, tetrahedrite‐tennantite, chalcopyrite and pyrite in microdruses and veinlets in the siliceous black ore from the Ezuri Kuroko deposit in the Hokuroku district of Japan. X‐ray microdiffractometry of this mineral gives strongest lines at 1.60, 1.32 and 1.09 Å, which are consistent with the known powder diffraction data of colusite. On the basis of 32 S atoms per formula unit, electron microprobe analyses yield empirical chemical formulae of (Cu24 0Fe0.3Zn1.0)σ25.3V1.9(As4.8Sb0.2)σ5.0Ge 1.3S32 for Ge‐bearing colusite in close association with sphalerite, and (Cu24.6Fe0.9)σ25.4V1.8(As4.1 Sb0.2)σ4.3Ge1.7S32 for that coexisting with chalcopyrite, consistent with the ideal formula of Cu24+xV2(As, Sb)6‐x(Sn, Ge)xS32 (x = 0 to 2) proposed by Spry et al. (1994) for this mineral species. The Ge‐bearing colusite mineralization is suggested to have occurred concurrently with consolidation of the siliceous black ore, possibly during hydrothermal modification in association with the igneous activity of the Ohtaki quartz diorite of the later Onnagawa stage. It is likely that biogenic siliceous ooze, a possible precursor of the siliceous black ore, may have served as an in situ source of Ge as well as other essential rare elements, leading to the formation of Ge‐bearing colusite during transformation or recrystallization of biogenic opal into a‐quartz. 相似文献
105.
Masayuki Komatsu 《Contributions to Mineralogy and Petrology》1980,74(4):329-338
Multiply-twinned clinoenstatite has been found in andesitic rocks from Chichi-jima and Mukojima in the Bonin Islands.The clinoenstatite occurs as (1) reaction rims around olivine, (2) composite crystals with bronzite, and (3) anhedral phenocrysts rimmed or included by bronzite.The clinoenstatite is chemically characterized by low contents of Ca (less than 0.5 wt.% oxide), Fs (9.2–11.5) and Al (less than 0.6 wt.% oxide) relative to the coexisting bronzite. The partition coefficient, K
D
op
cp
=(Mg/Fe2+)cp/(Mg/Fe2+)op between coexisting clinoenstatite and bronzite, ranges from 1.02 to 1.32 (average 1.17). The Fe2+/Mg+Fe2+ ratios of coexisting clinoenstatite and bronzite are different in different rock types, which suggests variable inversion temperatures of protoenstatite to orthopyroxene in boninite.Bronzite phenocrysts in a specimen, ranging from Fs15 to Fs30, coexist with augite phenocrysts, whereas those in the other specimens, ranging from Fs12 to Fs18, do not coexist with augite phenocrysts. These differences in petrographical nature and mineral chemistry among the specimens examined may be due to variations in their quenching stages.The boninite clinoenstatite and bronzite are relatively rich in Ca and Mg, compared with the Papuan and Mariana pyroxenes, which seems to depend upon the rock chemistry. 相似文献
106.
107.
108.
Joaquim I. Goes Kosei Sasaoka Helga do R. Gomes Sei-ichi Saitoh Toshiro Saino 《Journal of Oceanography》2004,60(1):75-91
This study documents the results of a multi-sensor satellite investigation aimed at comparing the seasonality and interannual variability of phytoplankton biomass and primary productivity (PP) in the western and eastern gyres of the subarctic Pacific. Satellite data helped discern several features, most importantly the existence of significant east-west gradients in the supply of nitrate in winter, in the consumption of nitrate by phytoplankton and in phytoplankton production and biomass accumulation over the growth season. In the western subarctic gyre many of these features appear to be regulated by the strength of sea surface winds through increased iron and nitrate inputs. Multiple regression analysis of data extracted from 12 boxes spanning different hydrographic regimes in the subarctic Pacific, showed that over 65% of the variations in PP in the subarctic Pacific could be explained solely on the basis of changes in the strength of sea surface winds and the intensity of incident irradiance (PAR). The dependence of PP on sea surface wind stress was far greater in the western subarctic Pacific Gyre (WSG), than in the Alaskan Gyre (ALG) due to diminishing impact of surface winds towards the east. Spring accumulation of phytoplankton biomass was greater in the WSG than in the ALG despite the higher rates of PP in the latter. This study assumes particular significance because it helps ascertain the existence of several sub-regions within the two broader domains of the WSG and the ALG. In addition, large interannual variations in phytoplankton biomass and PP were observed in the subarctic Pacific following the onset of the El-Niño event of 1997 and the transition to La-Niña conditions in 1999. These variations were largely the result of differences in meteorological and oceanographic conditions across the subarctic Pacific following the development of the El-Niño. 相似文献
109.
This paper examines the influence of aSargassum forest on the pH distribution in a small cove facing Wakasa Bay. The diurnal changes in spatial distribution of density and pH were observed in May 1977 during the season of luxuriant seaweed growth, and in August 1977 during the season of little growth. The observations were made at three-hour intervals for 24 hr in May, and 9 hr in August. During the period of strong density stratification, the observed pH distributions were divided into two types: (1) lower pH inshore and higher offshore in the upper layer in the evening and early morning, and (2) higher pH inshore and lower offshore in the daytime. During the period of weak stratification, a homogeneous pH distribution was observed. The pH distribution influenced bySargassum forest during the season of luxuriant growth was different from that during the season of little growth. The process that brought these spatial distributions is discussed. From early dawn to forenoon during the season of luxuriant growth, the heavier water, produced inshore by cooling through nocturnal radiation, cascaded as a stable laminar flow under the lighter water remaining under canopies of the forest and detached floating seaweeds. Reaching the offshore lower layer, and co-acting with algal respiration, this cascade influenced pH distribution. Some dynamical parameters for the process of cascading are calculated and examined. 相似文献
110.
Hiroshi Murakami Kosei Sasaoka Kohtaro Hosoda Hajime Fukushima Mitsuhiro Toratani Robert Frouin B. Greg Mitchell Mati Kahru Pierre-Yves Deschamps Dennis Clark Stephanie Flora Motoaki Kishino Sei-Ichi Saitoh Ichio Asanuma Akihiko Tanaka Hiroaki Sasaki Katsumi Yokouchi Yoko Kiyomoto Hiroaki Saito Cécile Dupouy Absornsuda Siripong Satsuki Matsumura Joji Ishizaka 《Journal of Oceanography》2006,62(3):373-393
The Global Imager (GLI) aboard the Advanced Earth Observing Satellite-II (ADEOS-II) made global observations from 2 April
2003 to 24 October 2003. In cooperation with several institutes and scientists, we obtained quality controlled match-ups between
GLI products and in-situ data, 116 for chlorophyll-a concentration (CHLA), 249 for normalized water-leaving radiance (nLw) at 443 nm, and 201 for
aerosol optical thickness at 865 nm (Tau_865) and Angstrom exponent between 520 and 865 nm (Angstrom). We evaluated the GLI
ocean color products and investigated the causes of errors using the match-ups. The median absolute percentage differences
(MedPD) between GLI and in-situ data were 14.1–35.7% for nLws at 380–565 nm, 52.5–74.8% nLws at 625–680 nm, 47.6% for Tau_865, 46.2% for Angstrom, and 46.6%
for CHLA, values that are comparable to the ocean-color products of other sensors. We found that some errors in GLI products
are correlated with observational conditions; nLw values were underestimated when nLw at 680 nm was high, CHLA was underestimated
in absorptive aerosol conditions, and Tau_865 was overestimated in sunglint regions. The error correlations indicate that
we need to improve the retrievals of the optical properties of absorptive aerosols and seawater and sea surface reflection
for further applications, including coastal monitoring and the combined use of products from multiple sensors. 相似文献